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What is Manganese Dioxide MnO2 Powder?

The roble had hit a record low after the West imposed sweeping sanctions on Russia for its aggression in Ukraine. Russia's president recently ordered exports of Russian gas to "unfriendly" countries to be settled in robles. The speaker of Russia's upper house of parliament said Moscow was prepared and could shift supplies to markets such as Asia if Europe refused to buy Russian energy.

European countries, which pay mostly in euros, say Russia has no right to reset contracts.  The G7 rejected Russia's demand and urged companies not to agree to pay in robles, saying most contracts stipulated payment in euros or dollars. Wholesale gas prices in Europe have risen further recently on concerns about potential supply disruptions.

The Kremlin spokesman said, "According to the March 31 deadline set by Russia's president, we are developing all payment methods to get a simple, understandable, and feasible system for relevant European and international buyers,"

The markets and prices of more commodities like the MnO2 would be affected because of the volatile international political situations.

Introduction to Manganese Dioxide MnO2 Powder
Manganese dioxide is also known as manganese peroxide or black manganese oxide. It is the oxide of tetravalent manganese. The chemical formula is MnO2. The fHm (298K) is -520.71kJ/mol, the melting point is 847, and the density is 5.026 g/cm3. The natural MnO2 exists in pyrolusite, and it is a black rhombic crystal or black-brown powder. It has a tetrahedral lattice, which is amphoteric manganese oxide. It is insoluble in water and nitric acid, but gives off oxygen and forms manganese sulfate in hot concentrated sulfuric acid and is chlorinated to manganese chloride in hydrochloric acid. It is fused with caustic soda and oxidant, giving off carbon dioxide to form permanganate. Manganese dioxide is a strong oxidant and can cause combustion and explosion by friction or co-heating with organic matter or other oxidable substances such as sulfur, sulfide, and phosphide. The product exhibits reducibility with strong oxidants such as hydrogen peroxide. MnO2 is converted into Mn2O3 when heated above 480 in air, and Mn3O4 when heated above 900. It is widely used in steelmaking, glass, ceramics, dry cells, etc.
 
In nature, it exists in the form of pyrolusite and hard manganese ore. It can be extracted from pyrolusite, and can also be prepared by heating decomposition of manganese nitrate or electrolytic manganese dioxide salt. γ -Mno2 is active and can be used as a cathode material for batteries to eliminate polarization. Manganese dioxide can be used as a rust remover, oxidizer, dry battery drying agent, and paint drying agent, also used in manganese salt preparation and the glass industry. 
 

Physicochemical Properties of Manganese Dioxide MnO2 Powder
For manganese dioxide, oxygen atoms are at the top of the octahedron corner and manganese atoms in the octahedron. Octahedron is connected to form a single chain or double chain, forming a tunnel structure of the gap, octahedron, or hexagonal dense or square dense accumulation. Oxidizability: Manganese dioxide is a non-salt oxide, non-amphoteric oxide which does not react with either acid or base. In the presence of reducing agents, is oxidizing. Such as manganese dioxide into the hydrogen flow heating to 1400K to get manganese oxide. Manganese dioxide is heated in an ammonia gas stream to obtain brown and black manganese trioxide. Manganese dioxide is reacted with concentrated hydrochloric acid to obtain manganese chloride, chlorine gas, and water.
 
In the presence of strong oxidants, it also exhibits reducibility. If the manganese dioxide, potassium carbonate, and potassium nitrate or potassium chlorate mixed melting, people can get dark green melt, melt it in water cooling people can get six valence manganese compound potassium manganate. It is a strong oxidant in an acid medium. Strong oxidant, does not burn on its own, but it aids combustion, so please do not place it with flammable materials.
 

Manganese Dioxide MnO2 Powder Properties
Other Names manganese oxide, MnO2 powder
CAS No. 1313-13-9
Compound Formula MnO2
Molecular Weight 86.94
Appearance black powder
Melting Point 535°C
Boiling Point N/A
Density 5.03g/cm3
Solubility in H2O insoluble
Exact Mass 86.9279

 

Manganese Dioxide MnO2 CAS 1313-13-9
 

 
Applications of Manganese Dioxide MnO2 Powder
1. Manganese dioxide is a very good decolorizing agent in the glass manufacturing industry, which can oxidize low ferric salt to high ferric salt, so that the blue-green glass into weak yellow.
2. In the electronic industry it is used to produce manganese zinc ferrite magnetic materials.  
3. Used as the raw material of iron and manganese alloy in the steelmaking industry and heating agent in the casting industry. 
4. Used in gas masks to absorb carbon monoxide. 
5. In the chemical industry it can be used as an oxidant, catalyst for organic synthesis, paint, and ink desiccant.
6. Used as an accelerant for match industry, as a raw material for glaze medicine of ceramics and enamel and manganese salt. 
7. Used for fireworks, water purification, iron removal, medicine, fertilizer and textile printing, dyeing, etc.  
8. Electrolytic manganese dioxide is an excellent depolarizing agent of battery. Compared with the dry battery produced by natural discharge manganese dioxide, it has the characteristics of large discharge capacity, strong activity, small volume, and long life, so electrolytic manganese dioxide has become a very important raw material in the battery industry. 
9. Electrolytic manganese dioxide due to its strong catalytic, oxidation/reduction, ion exchange, and adsorption capacity, after treatment and molding, it is a comprehensive excellent water purification filter material. Compared with the common use of activated carbon, zeolite, and other water purification filter material, it has a stronger ability to decolorize and remove metal. 
 

Main Supplier of Manganese Dioxide MnO2 Powder
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and Nanomaterials, including silicon powder, nitride powder, graphite powder, zinc sulfide, calcium nitride, 3D printing powder, etc.
If you are looking for high-quality manganese dioxide MnO2 powder, please feel free to contact us and send an inquiry. ([email protected])

 

The war in Russia and Ukraine is roiling global financial markets. Russia and Ukraine are important commodity suppliers in the world, so their conflict is bound to make a full impact on the global commodity supply. In view of this, the price of the MnO2 may continue to rise in the future.

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