3-12 Kinds of Concrete Additives Used in Refractory Castable, Plastic and Ramming Materials (3)
Analysts at JPMorgan recommended selling or "underweight" emerging market local currency sovereign debt because of the global impact of the Ukraine-Russia crisis.
JPMorgan estimated that fixed-income assets in emerging markets have lost 6-9 percent of their value since Russia invaded Ukraine a month ago, with nervousness about the war and its impact on global energy and food prices adding to existing pressures.
Some leading emerging market central banks are signaling that interest rates now need to rise faster than previously expected, which fuels fears of "stagflation". Stagflation means when high inflation and higher interest rates undermine economic growth.
With both the U.S. Federal Reserve and emerging market central banks raising interest rates, JPMorgan also said it made sense to "underweight" emerging market assets by taking advantage of the recent pullback in local currency bond yields relative to TREASURIES.
JPMorgan said major metals exporters such as South Africa, Chile, and Peru could still do well, but warned that emerging market fixed income assets now faced a more "stagflationary" trajectory.
The markets and prices of many commodities, metals, chemicals like the pce powder still face uncertainty.
The properties and varieties of concrete additives for refractories, especially refractory castables, ramming materials, plastics and other amorphous refractories are different. The role of an concrete additive is also different due to the difference of the amount of concrete additive, the type of binder used, the ingredients and so on. In the production process of amorphous refractories, the concrete additives mainly used can be divided into the following twelve categories according to their uses:
Defoamer can quickly escape the bubbles produced by amorphous refractories during mixing or vibration molding. Defoamer is also a surface active substance, and its ability to reduce liquid surface tension is much stronger than that of foaming agent. The strength of the formed liquid film is greatly reduced, the foam loses its stability, and the spreading speed on the liquid surface is faster, the faster the spreading speed is, the stronger the defoaming effect is. The types of defoamers include alcohols, fatty acids and fatty acid salts, organosilicon compounds and so on.
10. Anti-shrinkage agent
Anti-shrinkage agent can reduce or prevent the shrinkage caused by heating and use of refractories after forming, also known as volume stabilizer or expansive agent. Its anti-shrinkage principle is:
The anti-shrinkage agent will be pyrolyzed after high temperature heating, and the molar volume of the product is larger than that of the original material before pyrolysis, thus compensating the sintering shrinkage of the material. Such as kyanite anti-shrinkage agent.
After high temperature chemical reaction, the molar volume of the new phase is larger than that of the original reaction phase, thus the sintering shrinkage can be compensated. If α-Al2O3 is added to magnesia castables as anti-shrinkage agent, the volume expansion effect can be produced by the formation of alumina-magnesia spinel by high temperature reaction. For example, the bonded clay or silica powder is added to the high alumina castable to compensate the sintering shrinkage by the volume expansion effect of mullite produced at high temperature.
The added anti-shrinkage agent can not only change the crystal form of expansion in the process of high temperature heating, but also compensate the shrinkage of sintering. For example, in aluminosilicate castable or plastic, an appropriate amount of silica powder is added to compensate the sintering shrinkage of the matrix with the help of the volume expansion when quartz is transformed into cristobalite or cristobalite.
11. Preservation agent
The preservation agent can keep the construction performance unchanged or unchanged after the amorphous refractories are stored for a certain period of time. For example, Al2O3-SiO2 series refractory plastics and ramming materials, which are usually combined with phosphoric acid or aluminum dihydrogen phosphate, will react with Al2O3 in the material to form insoluble aluminum orthophosphate, which makes the mixture dry prematurely and lose its workability. Therefore, it is necessary to add a concealer which can form a complex with Al3+ ion to inhibit the formation of insoluble aluminum orthophosphate and prolong the shelf life. The preservatives used for plastics and ramming materials combined with phosphoric acid or aluminum dihydrogen phosphate are oxalic acid, citric acid, tartaric acid and so on. Sulfonic salicylic acid and dextrin also have the role of preservative.
Inhibitors can inhibit the expansion caused by the reaction of iron and iron compounds in amorphous refractories with acidic chemical binders, so it is also called anti-expansion agent. When acidic chemical binders (such as phosphoric acid, aluminum dihydrogen phosphate, aluminum sulfate, aluminum chloride and polyaluminum chloride, etc.) are used as binders, the mixture generally needs to go through trapped materials. in order to make the acid binder fully react with the metal iron or ferrous compounds contained in the mixture to release hydrogen, otherwise it will produce expansion and make the material become loose and porous and the strength decreases. If it is used directly without trapping material, an inhibitor must be added. Inhibitor is a kind of complexing agent, which can react with metallic iron to form a complex, which can inhibit expansion. These inhibitors include CrO3, diacetone alcohol, ferric phosphate and so on.
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Recently, Russia's deputy prime minister said that the number of countries buying Russian oil is increasing, including Asian countries. Russia will use the "East Siberia-Pacific" pipeline system to increase exports to Asian countries and promote the diversification of oil output.
He also said that Russian oil pce powder are expected to continue to increase in the future.