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What is Silicon Nitride Si3N4 Powder?

A recent poll in Britain found that public support for sanctions against Russia is falling as fuel and prices rise.  

The proportion of people willing to accept higher fuel prices as a result of western sanctions against Russia fell 14 percentage points to 36% from 50% in March, according to a survey conducted for the Telegraph by consultancy Redfield & Wilton Strategies.  

Global energy and fuel prices have soared since the start of the year and remain high because of the conflict between Russia and Ukraine and uncertainty over Russian supplies.  

The survey also found that 54% of people believe their own financial situation has worsened in the past year, up 12 percentage points from 42% two months ago. Sixty-two percent think things will get worse in the year ahead. Less than a third of respondents said they had received a pay rise to keep up with inflation, with two-thirds of those saying it was not enough to keep up with rising living costs.  

The figures suggest that public concern about the conflict with Ukraine is now likely to be overtaken by financial worries.  

Separately, the UK's consumer price index rose 7 percent this month from a year earlier, the highest since March 1992, according to figures released recently by the Office for National Statistics. In addition, a separate report released a few days ago by the Centre for Economics and Business Research said that real household disposable income in the UK will fall by 3% in 2022, equivalent to a loss of £2,320 per household, which would lead to the biggest drop in living standards since the 1950s. That is mainly because wages aren't keeping up with rising energy and fuel costs.  

The prices of other commodities like the Silicon Nitride powder are also expected to be influenced.

Introduction to Silicon Nitride Si3N4 Powder
Silicon nitride is a kind of inorganic substance, the chemical formula is Si3N4. The relative molecular mass is 140.28. Gray, white or off-white.
 

Physicochemical Properties of Silicon Nitride Si3N4 Powder
Si3N4 is a high-temperature insoluble compound. It has properties of high-temperature creep resistance. Hexagonal system. Crystals are hexahedral. The density of Si3N4 obtained by the reaction sintering method is 1.8-2.7 g/cm3, and the density of Si3N4 obtained by the hot-pressing method is 3.12-3.22 g/cm3. The Mohs hardness is 9~9.5, Vickers hardness is about 2200, and the microhardness is 32630MPa. The melting point is 1900 (under pressure). It usually decomposes at about 1900 at atmospheric pressure. Specific heat capacity is 0.71J/(g·K). The heat of formation is -751.57kJ/mol. The thermal conductivity is (2-155) W/(m·K). The linear expansion coefficient is 2.8~3.2×10-6/(20~1000). 
Insoluble in water. Soluble in hydrofluoric acid. The temperature at which oxidation begins in the air is 1300~1400. The specific volume resistance is 1.4×105 ·m at 20 and 4×108 ·m at 500. The elastic modulus is 28420~46060MPa. The compressive strength is 490MPa (reaction sintering). At 1285, it reacts with dicalcium diazide to form calcium diazide. At 600, the transition metal is reduced and nitrogen oxides are released. The bending strength is 147MPa. It can be made by heating silicon powder in nitrogen or reacting silicon halide with ammonia. The resistivity is between 10^15-10^16Ω.cm. It can be used as high-temperature ceramic material. 
Except for hydrofluoric acid and hot phosphoric acid, silicon nitride does not react with other inorganic acids and has strong corrosion resistance. 
 

Silicon Nitride Si3N4 Powder Properties
Other Names silicon (IV) nitride, α-Si3N4, SiN, trisilicon tetranitride, Si3N4 powder
CAS No. 12033-89-5
Compound Formula Si3N4
Molecular Weight 140.28
Appearance white to gray powder
Melting Point 1900°C
Boiling Point N/A
Density 2.2-3.5g/cm3
Solubility in H2O insoluble
Exact Mass 139.943

 

Silicon Nitride Si3N4 Powder CAS 12033-89-5
 

 
 

Applications of Silicon Nitride Si3N4 Powder
Silicon nitride ceramic material has the advantages of high thermal stability, high oxidation resistance, and high dimensional accuracy. Because the silicon nitride is the covalent compound with high bond strength, and it will form an oxide film in the air, it has good chemical stability. Silicon nitride is not oxidized below 1200, and a protective film can be formed at 1200~1600 to prevent it from further oxidation. Silicon nitride is not infiltrated or corroded by aluminum, lead, tin, silver, brass, nickel, and many other molten metals or alloys, but can be corroded by magnesium, nickel-chromium alloy, stainless steel, and other molten liquids.
Silicon nitride ceramic materials can be used in high-temperature engineering components, advanced refractory in the metallurgical industry, corrosion-resistant components and sealing components in the chemical industry, machining industry tools, and cutting tools.
Because silicon nitride can form a strong bond with silicon carbide, alumina, thorium dioxide, boron nitride, etc., it can be used as a bond material to modify with different proportions. 
In addition, silicon nitride can be used in solar cells. After the silicon nitride film is plated by the PECVD method, not only can it be used as an antireflection film to reduce the reflection of the incident light, but also, in the deposition process of a silicon nitride film, the hydrogen atom of the reaction product enters the silicon nitride film and silicon wafer, playing a role of passivation defect. The ratio of silicon nitride to silicon nitrogen atoms is not a strict 4:3, but fluctuates within a certain range according to different technological conditions. Different atomic ratios correspond to different physical properties of the film. 
Also, it can be used in ultra-high temperature gas turbines, aircraft engines, electric furnaces, etc. 
 

Main Supplier of Silicon Nitride Si3N4 Powder
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and Nanomaterials, including silicon powder, nitride powder, graphite powder, zinc sulfide, calcium nitride, 3D printing powder, etc.
If you are looking for high-quality silicon nitride Si3N4 powder, please feel free to contact us and send an inquiry. ([email protected])

 

The development of the Russia-Ukraine conflict will continue to dominate the commodity prices such as the Silicon Nitride powder in the future. If the conflict eases or cools, Russia and Ukraine go back to negotiate, commodity prices would fall. However, if the situation between Russia and Ukraine deteriorates further, or evolves into a full-scale war, the price of the Silicon Nitride powder is predicted to see further improvement over the coming days.

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